Abstrakt

In this work, a critical evaluation of silver ion migration at the surface of Al0.04Sc0.06Zr0.9O1.95 (AlScZrO) electrolyte is explored in intermediate temperature solid oxide fuel cells (IT-SOFCs). The behaviour of silver is systematically studied at the operating conditions of silver as a cathode, anode, or sealant in IT-SOFCs. The results to those obtained at the surface of other electrolytes (gadolinia doped ceria, samaria doped ceria and yttria-stabilized zirconia) are also analysed. In the case of cathodic polarization, a thick silver deposit is formed around the electrode on the surface of the electrolyte, which may lead to the short-circuiting of the electrodes. While for the anodic polarization, oxygen bubbles are formed between the electrode and electrolyte, leading the delamination of electrode. Silver can also migrate from unpolarized parts of the cell such as sealants. Therefore, Issues related to the application of silver in IT-SOFCs should be concerned by the scientific community.